- 英文名称
- (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
- 分子式
- C36H52ClMnN2O2
- 分子量
- 635.2
- 中文别名
- (1S,2S)-(+)-[1,2-环己烷二胺氮-N,N'-双(3,5-二-叔丁基亚水杨基)]氯化锰(III); (S,S)-(+)-N,N′-双(3,5-二-叔丁基亚水杨基)-1,2-环己二胺氯化锰(III); (S,S)-JACOBSEN 催化剂; (1S,2S)-(+)-(1,2-环己烷二氨基-N,N-双(3,5-二丁基亚水杨基)锰(Ⅲ)氯化物; (S,S)-(+)N,N'-双(3,5-二叔丁基水杨基)-1,2-环己二胺氯化锰; (S,S)-雅可布逊催化剂氯化锰络合物; (S,S)-(+)-N,N′-双(3,5-二-叔-丁基亚水杨基)-1,2-环己二氨基氯化锰(III); (S,S)-雅可布逊催化剂; (+)-BIS(3,5-DI-T-BU-SALICYL.)-1,2-CYCLOHEXANEDIAMINO-MN CL; (S,S)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MN-CL; (1S,2S)-(+)-(1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene))manganese(III)chloride; (S,S)-Jacobsencat.; (1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III)chloride; (S,S)(+)N,N'-Bis(3,5-di-tbutylsalicylidene)1,2-chexanediaminomanganese(iii)chloride; (S,S)-(+)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chlo; Jacobsen catalyst; JACOBSEN'S CATALYST; (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride
- 用途
- 非官能化烯烃类的Salen(Mn)-催化不对称环氧化反应，获得各种底物（特别是顺式-烯烃）的高对映立体选择性和产量；用于合成紫杉醇侧链和顺式-1-氨基-2-茚醇；用于硅烯醇醚的不对称α-羟基化；作为各种烯烃不对称环氧化反应的催化剂。
