3,4-环氧四氢呋喃是一种用多用途双核铬催化剂, 可从环氧化物中制备各种可降解的聚合物。
医药; 农药
合成路线 1（1. 合成：285-69-8）
产率：84.6%
合成条件：With 3-chloro-benzenecarboperoxoic acid In tetrahydrofuran at 0 - 20℃;
实验步骤：步骤1：使用冰水浴在0℃下向24a（5.04g，0.072mol）在150mL DCM中的溶液中加入85％mCPBA（18.86g，0.093mol）。 将混合物在室温下搅拌过周末。 滤出沉淀物。 用饱和NaHCO 3水溶液，水和盐水成功洗涤滤液。 将有机层用无水Na 2 SO 4干燥并浓缩，得到白色固体和黄色油状物的混合物（5.24g，84.6％）。
参考文献：
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