化学合成。
化学合成
合成路线 1（1. 合成：17178-10-8）
产率：95%
合成条件：With tetrabutylammomium bromide; sodium hydroxide In dichloromethane at 20℃; for 24 h;
实验步骤：搅拌2-甲氧基乙醇（7.36mL，0.10mol）和催化量的TBAB（四正丁基溴化铵）在二氯甲烷中的溶液，随后加入NaOH（水溶液，30％，15mL）。 逐滴加入对甲苯磺酰氯的二氯甲烷溶液。 将混合物在室温下搅拌24小时，然后用蒸馏水洗涤三次。 将产物用Na 2 SO 4干燥，减压除去溶剂，得到黄色油状物。 产量95％。 IR（KBr，cm 1）选择的带：3468（m），2938（s），2889（s），1597（m），1455（m），1357（s），1184（s），1130（m）， 1101（m），1018（m），919（m），821（m）。 1H-NMR（400MHz，CD3COCD3）：3.20（s，3H），3.48（t，J = 4.6Hz，2H），4.08（t，J = 4.6Hz，2H），7.71（d，J = 8.4Hz， 2H），7.28（d，J = 8.4Hz，2H），2.36（s，3H）。。计算器。 C10H14SO4的分析计算值：C，52.16; H，6.13。 实测值：C，52.09; H，6.17。
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