3,5-二苄氧基苯甲醛主要用于化学合成,也可用作研究用化合物。
化学合成; 研究用化合物
合成路线 1(14615-72-6)
- 步骤: 向3,5-双(苄氧基)苄醇(9.9g,31.0mmol)的CH₂Cl₂(140mL)溶液中加入DMSO(22mL,0.31mol)和二异丙基乙胺(26.92mL,0.154mol);将混合物冷却至0℃并加入SO₃·吡啶(14.76g,92.73mmol);在0℃下搅拌1小时,用饱和Na₂S₂O₃水溶液(310mL)淬灭;用乙酸乙酯(3×200mL)萃取,合并有机层,用MgSO₄干燥;蒸发溶剂,通过硅胶柱色谱法(CH₂Cl₂)纯化,得到产物。
- 条件: With sulfur trioxide pyridine complex; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine In dichloromethane at 0℃; for 1 h
- 收率: 93%
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