1829-34-1 3-溴-2-羟基苯甲醛

中文名称: 3-溴-2-羟基苯甲醛
英文名称: 3-Bromo-2-hydroxybenzaldehyde
CAS号

词条详情加载中…

名称和标识

中文名: 3-溴-2-羟基苯甲醛
英文名: 3-Bromo-2-hydroxybenzaldehyde
CAS号: 1829-34-1
分子式: C7H5BrO2
分子量: 201.02
中文别名: 3-溴柳醛; 3-溴水杨醛; 2-羟基-3-溴苯甲醛
英文别名: 3-Bromosalicylaldehyde; 2-Bromo-6-formylphenol; 2-Hydroxy-3-bromobenzaldehyde; 3-bromo-2-hydroxy-benzaldehyde; Benzaldehyde, 3-bromo-2-hydroxy-; 3-BROMSALICYLALDEHYDE; bromosalicylaldehyde

物化属性

LogP: 2.70
MLOGP: 1.55
Num. H-bond acceptors: 2.0
Num. H-bond donors: 1.0
Num. rotatable bonds: 1

安全信息

安全说明

运输方式：冰袋运输。危险性质：非危险化学品。WGK Germany:3。危险说明：有害。海关编码:29130000。存储类别:11 - 可燃固体。危险性类别：急性毒性类别4（经口）、眼部刺激类别2、经皮刺激类别2、特异性靶器官毒性-一次接触，类别3。

生产及用途

用途与制备

3-溴柳醛可作为药物分子和有机合成中间体，用于实验室有机合成中。

医药; 有机合成

路线1：

步骤: 将B化合物（1.94g，9.19mmol）在CH₂Cl₂（100mL）中的溶液冷却至-78℃，通入3% O₃/O₂气体混合物至蓝色持续（约35分钟）；氮气吹扫后加入二甲基硫醚（5mL），温热至室温反应4小时；蒸发溶液后，在MeOH（8mL）中加入水（8mL）和碳酸钾（1.1g，80mmol），氩气下加热至55℃反应1小时；冷却后用1M HCl中和至pH7，CH₂Cl₂萃取两次，合并有机相干燥（MgSO₄）、蒸发，快速色谱纯化得目标产物。
条件: Stage #1: O₃/O₂（3%），-78℃，0.58h；Stage #2: 二甲基硫醚，-78-20℃，4h；Stage #3: 水、碳酸钾，55℃，1h；
产率: 80%
参考文献: US2003/225091, 1993, Chemical and Pharmaceutical Bulletin, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 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2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 2003, 200

1829-34-1 3-溴-2-羟基苯甲醛 - 化工 AI 网