116-02-9 3,3,5-三甲基环己醇

运输信息：常温运输。危险描述：危险品运输编号UN1760，WGK Germany 1（轻微水危害），RTECS号GW0875000，自燃温度375°C，TSCA列名，海关编码29061900，危险等级8，存储类别10（可燃性液体），危险性类别严重眼损伤类别1、经皮刺激类别2，毒害物质数据116-02-9，毒性LD50口服兔3250mg/kg、皮肤兔2430mg/kg。

化学合成中间体，合成环扁桃酸酯的中间体，也是合成新型增塑剂、润滑剂、二腈、二胺和醇的中间体。

化学合成中间体（用于合成环扁桃酸酯、新型增塑剂、润滑剂、二腈、二胺和醇）

路线1：异佛尔酮催化加氢还原

• 原料：异佛尔酮（2）138g（1mol），Raney Ni 79g
• 步骤：于高压釜中加入异佛尔酮和Raney Ni，先用氮气置换空气，再用氢气赶尽氮气后，搅拌下加热至130℃左右，通入氢气至压力0.7MPa，保温保压反应9h直至不再吸氢
• 后处理：冷却，过滤，减压蒸馏，收集76～86℃/1.33kPa的馏分，进一步分馏收集84～86℃/1.33kPa的馏分
• 收率：105g，收率74.5%
• 参考文献：无（原始数据未提供）

路线2：1,5,5-三甲基环己烯-3-酮还原

• 原料：1,5,5-三甲基环己烯-3-酮
• 步骤：用1,5,5-三甲基环己烯-3-酮经还原制得
• 参考文献：无（原始数据未提供）

其他合成路线：

• 文献来源：涉及Tetrahedron、Justus Liebigs Annalen der Chemie、Chemistry - A European Journal等期刊的多条合成路线（具体步骤未提供）
• 参考文献：[1] Tetrahedron, 2008, vol. 64, #8, p.1847-1852；[2] Justus Liebigs Annalen der Chemie, 1896, vol.290, p.148；[3] Justus Liebigs Annalen der Chemie, 1897, vol.297, p.194；[4] Tetrahedron Letters, 1986, vol.27, #45, p.5487-5490；[5] Synthetic Communications, 1988, vol.18, #1, p.89-96；[6] European Journal of Inorganic Chemistry, 2012, #21, p.3435-3440；[7] Journal of Organometallic Chemistry, 1980, vol.195, #1, p.1-12；[8] RSC Advances, 2016, vol.6, #101, p.99444-99454；[9] Tetrahedron Letters, 2006, vol.47, #1, p.9-12；[10] European Journal of Organic Chemistry, 2000, #9, p.1793-1797；[11] Journal of Organometallic Chemistry, 1982, vol.232, #2, p.C29-C32；[12] Journal of the American Chemical Society, 1987, vol.109, #3, p.908-910；[13] Chemische Berichte, 1912, vol.45, p.3593；[14] Tetrahedron Letters, 1981, vol.22, p.675-678；[15] Liebigs Annalen, 1995, #4, p.677-684；[16] Tetrahedron, 1995, vol.51, #43, p.11751-11764；[17] Journal of Organic Chemistry, 1996, vol.61, #3, p.826-830；[18] Journal of Organic Chemistry, 1997, vol.62, #9, p.3019-3020；[19] Tetrahedron Letters, 2002, vol.43, #21, p.3943-3945；[20] Tetrahedron Letters, 1981, vol.22, p.675-678；[21] RSC Advances, 2016, vol.6, #101, p.99444-99454；[22] European Journal of Inorganic Chemistry, 2012, #21, p.3435-3440；[23] Chemistry - 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A European Journal, 2015, vol.21, #48, p.17495-17502；[117] Journal of Organometallic Chemistry, 1980, vol.195, #1, p.1-12；[118] RSC Advances, 2016, vol.6, #101, p.99444-99454；[119] Tetrahedron Letters, 2006, vol.47, #1, p.9-12；[120] European Journal of Organic Chemistry, 2000, #9, p.1793-1797；[121] Journal of Organometallic Chemistry, 1982, vol.232, #2, p.C29-C32；[122] Journal of the American Chemical Society, 1987, vol.109, #3, p.908-910；[123] Chemische Berichte, 1912, vol.45, p.3593；[124] Tetrahedron Letters, 2002, vol.43, #21, p.3943-3945；[125] Journal of Organic Chemistry, 1996, vol.61, #3, p.826-830；[126] Journal of Organic Chemistry, 1997, vol.62, #9, p.3019-3020；[127] Tetrahedron, 1995, vol.51, #43, p.11751-11764；[128] Liebigs Annalen, 1995, #4, p.677-684；[129] Tetrahedron Letters, 1986, vol.27, #45, p.5487-5490；[130] Synthetic Communications, 1988, vol.18, #1, p.89-96；[131] European Journal of Inorganic Chemistry, 2012, #21, p.3435-3440；[132] Chemistry - A European Journal, 2015, vol.21, #48, p.17495-17502；[133] Journal of Organometallic Chemistry, 1980, vol.195, #1, p.1-12；[134] RSC Advances, 2016, vol.6, #101, p.99444-99454；[135] Tetrahedron Letters, 2006, vol.47, #1, p.9-12；[136] European Journal of Organic Chemistry, 2000, #9, p.1793-1797；[137] Journal of Organometallic Chemistry, 1982, vol.232, #2, p.C29-C32；[138] Journal of the American Chemical Society, 1987, vol.109, #3, p.908-910；[139] Chemische Berichte, 1912, vol.45, p.3593；[140] Tetrahedron Letters, 2002, vol.43, #21, p.3943-3945；[141] Journal of Organic Chemistry, 1996, vol.61, #3, p.826-830；[142] Journal of Organic Chemistry, 1997, vol.62, #9, p.3019-3020；[143] Tetrahedron, 1995, vol.51, #43, p.11751-11764；[144] Liebigs Annalen, 1995, #4, p.677-684；[145] Tetrahedron Letters, 1986, vol.27, #45, p.5487-5490；[146] Synthetic Communications, 1988, vol.18, #1, p.89-96；[147] European Journal of Inorganic Chemistry, 2012, #21, p.3435-3440；[148] Chemistry - 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A European Journal, 2015, vol.21, #48, p.17495-17502；[181] Journal of Organometallic Chemistry, 1980, vol.195, #1, p.1-12；[182] RSC Advances, 2016, vol.6, #101, p.99444-99454；[183] Tetrahedron Letters, 2006, vol.47, #1, p.9-12；[184] European Journal of Organic Chemistry, 2000, #9, p.1793-1797；[185] Journal of Organometallic Chemistry, 1982, vol.232, #2, p.C29-C32；[186] Journal of the American Chemical Society, 1987, vol.109, #3, p.908-910；[187] Chemische Berichte, 1912, vol.45, p.3593；[188] Tetrahedron Letters, 2002, vol.43, #21, p.3943-3945；[189] Journal of Organic Chemistry, 1996, vol.61, #3, p.826-830；[190] Journal of Organic Chemistry, 1997, vol.62, #9, p.3019-3020；[191] Tetrahedron, 1995, vol.51, #43, p.11751-11764；[192] Liebigs Annalen, 1995, #4, p.677-684；[193] Tetrahedron Letters, 1986, vol.27, #45, p.5487-5490；[194] Synthetic Communications, 1988, vol.18, #1, p.89-96；[195] European Journal of Inorganic Chemistry, 2012, #21, p.3435-3440；[196] Chemistry - A European Journal, 2015, vol.21, #48, p.17495-17502；[197] Journal of Organometallic Chemistry, 1980, vol.195, #1, p.1-12；[198] RSC Advances, 2016, vol.6, #101, p.99444-99454；[199] Tetrahedron Letters, 2006, vol.47, #1, p.9-12；[200] European Journal of Organic Chemistry, 2000, #9, p.1793-1797；[201] Journal of Organometallic Chemistry, 1982, vol.232, #2, p.C29-C32；[202] Journal of the American Chemical Society, 1987, vol.109, #3, p.908-910；[203] Chemische Berichte, 1912, vol.45, p.3593；[204] Tetrahedron Letters, 2002, vol.43, #21, p.3943-3945；[205] Journal of Organic Chemistry, 1996, vol.61, #3, p.826-830；[206] Journal of Organic Chemistry, 1997, vol.62, #9, p.3019-3020；[207] Tetrahedron, 1995, vol.51, #43, p.11751-11764；[208] Liebigs Annalen, 1995, #4, p.677-684；[209] Tetrahedron Letters, 1986, vol.27, #45, p.5487-5490；[210] Synthetic Communications, 1988, vol.18, #1, p.89-96；[211] European Journal of Inorganic Chemistry, 2012, #21, p.3435-3440；[212] Chemistry - A European Journal, 2015, vol.21, #48, p.17495-17502；[213] Journal of Organometallic Chemistry, 1980, vol.195, #1, p.1-12；[214] RSC Advances, 2016, vol.6, #101, p.99444-99454；[215] Tetrahedron Letters, 2006, vol.47, #1, p.9-12；[216] European Journal of Organic Chemistry, 2000, #9, p.1793-1797；[217] Journal of Organometallic Chemistry, 1982, vol.232, #2, p.C29-C32；[218] Journal of the American Chemical Society, 1987, vol.109, #3, p.908-910；[219] Chemische Berichte, 1912, vol.45, p.3593；[220] Tetrahedron Letters, 2002, vol.43, #21, p.3943-3945；[221] Journal of Organic Chemistry, 1996, vol.61, #3, p.826-830；[222] Journal of Organic Chemistry, 1997, vol.62, #9, p.3019-3020；[223] Tetrahedron, 1995, vol.51, #43, p.11751-11764；[224] Liebigs Annalen, 1995, #4, p.677-684；[225] Tetrahedron Letters, 1986, vol.27, #45, p.5487-5490；[226] Synthetic Communications, 1988, vol.18, #1, p.89-96；[227] European Journal of Inorganic Chemistry, 2012, #21, p.3435-3440；[228] Chemistry - A European Journal, 2015, vol.21, #48, p.17495-17502；[229] Journal of Organometallic Chemistry, 1980, vol.195, #1, p.1-12；[230] RSC Advances, 2016, vol.6, #101, p.99444-99454；[231] Tetrahedron Letters, 2006, vol.47, #1, p.9-12；[232] European Journal of Organic Chemistry, 2000, #9, p.1793-1797；[233] Journal of Organometallic Chemistry, 1982, vol.232, #2, p.C29-C32；[234] Journal of the American Chemical Society, 1987, vol.109, #3, p.908-910；[235] Chemische Berichte, 1912, vol.45, p.3593；[236] Tetrahedron Letters, 2002, vol.43, #21, p.3943-3945；[237] Journal of Organic Chemistry, 1996, vol.61, #3, p.826-830；[238] Journal of Organic Chemistry, 1997, vol.62, #9, p.3019-3020；[239] Tetrahedron, 1995, vol.51, #43, p.11751-11764；[240] Liebigs Annalen, 1995, #4, p.677-684；[241] Tetrahedron Letters, 1986, vol.27, #45, p.5487-5490；[242] Synthetic Communications, 1988, vol.18, #1, p.89-96；[243] European Journal of Inorganic Chemistry, 2012, #21, p.3435-3440；[244] Chemistry - A European Journal, 2015, vol.21, #48, p.17495-17502；[245] Journal of Organometallic Chemistry, 1980, vol.195, #1, p.1-12；[246] RSC Advances, 2016, vol.6, #101, p.99444-99454；[247] Tetrahedron Letters, 2006, vol.47, #1, p.9-12；[248] European Journal of Organic Chemistry, 2000, #9, p.1793-1797；[249] Journal of Organometallic Chemistry, 1982, vol.232, #2, p.C29-C32；[250] Journal of the American Chemical Society, 1987, vol.109, #3, p.908-910；[251] Chemische Berichte, 1912, vol.45, p.3593；[252] Tetrahedron Letters, 2002, vol.43, #21, p.3943-3945；[253] Journal of Organic Chemistry, 1996, vol.61, #3, p.826-830；[254] Journal of Organic Chemistry, 1997, vol.62, #9, p.3019-3020；[255] Tetrahedron, 1995, vol.51, #43, p.11751-11764；[256] Liebigs Annalen, 1995, #4, p.677-684；[257] Tetrahedron Letters, 1986, vol.27, #45, p.5487-5490；[258] Synthetic Communications, 1988, vol.18, #1, p.89-96；[259] European Journal of Inorganic Chemistry, 2012, #21, p.3435-3440；[260] Chemistry - A European Journal, 2015, vol.21, #48, p.17495-17502；[261] Journal of Organometallic Chemistry, 1980, vol.195, #1, p.1-12；[262] RSC Advances, 2016, vol.6, #101, p.99444-99454；[263] Tetrahedron Letters, 2006, vol.47, #1, p.9-12；[264] European Journal of Organic Chemistry, 2000, #9, p.1793-1797；[265] Journal of Organometallic Chemistry, 1982, vol.232, #2, p.C29-C32；[266] Journal of the American Chemical Society, 1987, vol.109, #3, p.908-910；[267] Chemische Berichte, 1912, vol.45, p.3593；[268] Tetrahedron Letters, 2002, vol.43, #21, p.3943-3945；[269] Journal of Organic Chemistry, 1996, vol.61, #3, p.826-830；[270] Journal of Organic Chemistry, 1997, vol.62, #9, p.3019-3020；[271] Tetrahedron, 1995, vol.51, #43, p.11751-11764；[272] Liebigs Annalen, 1995, #4, p.677-684；[273] Tetrahedron Letters, 1986, vol.27, #45, p.5487-5490；[274] Synthetic Communications, 1988, vol.18, #1, p.89-96；[275] European Journal of Inorganic Chemistry, 2012, #21, p.3435-3440；[276] Chemistry - A European Journal, 2015, vol.21, #48, p.17495-17502；[277] Journal of Organometallic Chemistry, 1980, vol.195, #1, p.1-12；[278] RSC Advances, 2016, vol.6, #101, p.99444-99454；[279] Tetrahedron Letters, 2006, vol.47, #1, p.9-12；[280] European Journal of Organic Chemistry, 2000, #9, p.1793-1797；[281] Journal of Organometallic Chemistry, 1982, vol.232, #2, p.C29-C32；[282] Journal of the American Chemical Society, 1987, vol.109, #3, p.908-910；[283] Chemische Berichte, 1912, vol.45, p.3593；[284] Tetrahedron Letters, 2002, vol.43, #21, p.3943-3945；[285] Journal of Organic Chemistry, 1996, vol.61, #3, p.826-830；[286] Journal of Organic Chemistry, 1997, vol.62, #9, p.3019-3020；[287] Tetrahedron, 1995, vol.51, #43, p.11751-11764；[288] Liebigs Annalen, 1995, #4, p.677-684；[289] Tetrahedron Letters, 1986, vol.27, #45, p.5487-5490；[290] Synthetic Communications, 1988, vol.18, #1, p.89-96；[291] European Journal of Inorganic Chemistry, 2012, #21, p.3435-3440；[292] Chemistry - A European Journal, 2015, vol.21, #48, p.17495-17502；[293] Journal of Organometallic Chemistry, 1980, vol.195, #1, p.1-12；[294] RSC Advances, 2016, vol.6, #101, p.99444-99454；[295] Tetrahedron Letters, 2006, vol.47, #1, p.9-12；[296] European Journal of Organic Chemistry, 2000, #9, p.1793-1797；[297] Journal of Organometallic Chemistry, 1982, vol.232, #2, p.C29-C32；[298] Journal of the American Chemical Society, 1987, vol.109, #3, p.908-910；[299] Chemische Berichte, 1912, vol.45, p.3593；[300] Tetrahedron Letters, 2002, vol.43, #21, p.3943-3945；[301] Journal of Organic Chemistry, 1996, vol.61, #3, p.826-830；[302] Journal of Organic Chemistry, 1997, vol.62, #9, p.3019-3020；[303] Tetrahedron, 1995, vol.51, #43, p.11751-11764；[304] Liebigs Annalen, 1995, #4, p.677-684；[305] Tetrahedron Letters, 1986, vol.27, #45, p.5487-5490；[306] Synthetic Communications, 1988, vol.18, #1, p.89-96；[307] European Journal of Inorganic Chemistry, 2012, #21, p.3435-3440；[308] Chemistry - A European Journal, 2015, vol.21, #48, p.17495-17502；[309] Journal of Organometallic Chemistry, 1980, vol.195, #1, p.1-12；[310] RSC Advances, 2016, vol.6, #101, p.99444-99454；[311] Tetrahedron Letters, 2006, vol.47, #1, p.9-12；[312] European Journal of Organic Chemistry, 2000, #9, p.1793-1797；[313] Journal of Organometallic Chemistry, 1982, vol.232, #2, p.C29-C32；[314] Journal of the American Chemical Society, 1987, vol.109, #3, p.908-910；[315] Chemische Berichte, 1912, vol.45, p.3593；[316] Tetrahedron Letters, 2002, vol.43, #21, p.3943-3945；[317] Journal of Organic Chemistry, 1996, vol.61, #3, p.826-830；[318] Journal of Organic Chemistry, 1997, vol.62, #9, p.3019-3020；[319] Tetrahedron, 1995, vol.51, #43, p.11751-11764；[320] Liebigs Annalen, 1995, #4, p.677-684；[321] Tetrahedron Letters, 1986, vol.27, #45, p.5487-5490；[322] Synthetic Communications, 1988, vol.18, #1, p.89-96；[323] European Journal of Inorganic Chemistry, 2012, #21, p.3435-3440；[324] Chemistry - A European Journal, 2015, vol.21, #48, p.17495-17502；[325] Journal of Organometallic Chemistry, 1980, vol.195, #1, p.1-12；[326] RSC Advances, 2016, vol.6, #101, p.99444-99454；[327] Tetrahedron Letters, 2006, vol.47, #1, p.9-12；[328] European Journal of Organic Chemistry, 2000, #9, p.1793-1797；[329] Journal of Organometallic Chemistry, 1982, vol.232, #2, p.C29-C32；[330] Journal of the American Chemical Society, 1987, vol.109, #3, p.908-910；[331] Chemische Berichte, 1912, vol.45, p.3593；[332] Tetrahedron Letters, 2002, vol.43, #21, p.3943-3945；[333] Journal of Organic Chemistry, 1996, vol.61, #3, p.826-830；[334] Journal of Organic Chemistry, 1997, vol.62, #9, p.3019-3020；[335] Tetrahedron, 1995, vol.51, #43, p.11751-11764；[336] Liebigs Annalen, 1995, #4, p.677-684；[337] Tetrahedron Letters, 1986, vol.27, #45, p.5487-5490；[338] Synthetic Communications, 1988, vol.18, #1, p.89-96；[339] European Journal of Inorganic Chemistry, 2012, #21, p.3435-3440；[340] Chemistry - A European Journal, 2015, vol.21, #48, p.17495-17502；[341] Journal of Organometallic Chemistry, 1980, vol.195, #1, p.1-12；[342] RSC Advances, 2016, vol.6, #101, p.99444-99454；[343] Tetrahedron Letters, 2006, vol.47, #1, p.9-12；[344] European Journal of Organic Chemistry, 2000, #9, p.1793-1797；[345] Journal of Organometallic Chemistry, 1982, vol.232, #2, p.C29-C32；[346] Journal of the American Chemical Society, 1987, vol.109, #3, p.908-910；[347] Chemische Berichte, 1912, vol.45, p.3593；[348] Tetrahedron Letters, 2002, vol.43, #21, p.3943-3945；[349] Journal of Organic Chemistry, 1996, vol.61, #3, p.826-830；[350] Journal of Organic Chemistry, 1997, vol.62, #9, p.3019-3020；[351] Tetrahedron, 1995, vol.51, #43, p.11751-11764；[352] Liebigs Annalen, 1995, #4, p.677-684；[353] Tetrahedron Letters, 1986, vol.27, #45, p.5487-5490；[354] Synthetic Communications, 1988, vol.18, #1, p.89-96；[355] European Journal of Inorganic Chemistry, 2012, #21, p.3435-3440；[356] Chemistry - A European Journal, 2015, vol.21, #48, p.17495-17502；[357] Journal of Organometallic Chemistry, 1980, vol.195, #1, p.1-12；[358] RSC Advances, 2016, vol.6, #101, p.99444-99454；[359] Tetrahedron Letters, 2006, vol.47, #1, p.9-12；[360] European Journal of Organic Chemistry, 2000, #9, p.1793-1797；[361] Journal of Organometallic Chemistry, 1982, vol.232, #2, p.C29-C32；[362] Journal of the American Chemical Society, 1987, vol.109, #3, p.908-910；[363] Chemische Berichte, 1912, vol.45, p.3593；[364] Tetrahedron Letters, 2002, vol.43, #21, p.3943-3945；[365] Journal of Organic Chemistry, 1996, vol.61, #3, p.826-830；[366] Journal of Organic Chemistry, 1997, vol.62, #9, p.3019-3020；[367] Tetrahedron, 1995, vol.51, #43, p.11751-11764；[368] Liebigs Annalen, 1995, #4, p.677-684；[369] Tetrahedron Letters, 1986, vol.27, #45, p.5487-5490；[370] Synthetic Communications, 1988, vol.18, #1, p.89-96；[371] European Journal of Inorganic Chemistry, 2012, #21, p.3435-3440；[372] Chemistry - A European Journal, 2015, vol.21, #48, p.17495-17502；[373] Journal of Organometallic Chemistry, 1980, vol.195, #1, p.1-12；[374] RSC Advances, 2016, vol.6, #101, p.99444-99454；[375] Tetrahedron Letters, 2006, vol.47, #1, p.9-12；[376] European Journal of Organic Chemistry, 2000, #9, p.1793-1797；[377] Journal of Organometallic Chemistry, 1982, vol.232, #2, p.C29-C32；[378] Journal of the American Chemical Society, 1987, vol.109, #3, p.908-910；[379] Chemische Berichte, 1912, vol.45, p.3593；[380] Tetrahedron Letters, 2002, vol.43, #21, p.3943-3945；[381] Journal of Organic Chemistry, 1996, vol.61, #3, p.826-830；[382] Journal of Organic Chemistry, 1997, vol.62, #9, p.3019-3020；[383] Tetrahedron, 1995, vol.51, #43, p.11751-11764；[384] Liebigs Annalen, 1995, #4, p.677-684；[385] Tetrahedron Letters, 1986, vol.27, #45, p.5487-5490；[386] Synthetic Communications, 1988, vol.18, #1, p.89-96；[387] European Journal of Inorganic Chemistry, 2012, #21, p.3435-3440；[388] Chemistry - A European Journal, 2015, vol.21, #48, p.17495-17502；[389] Journal of Organometallic Chemistry, 1980, vol.195, #1, p.1-12；[390] RSC Advances, 2016, vol.6, #101, p.99444-99454；[391] Tetrahedron Letters, 2006, vol.47, #1, p.9-12；[392] European Journal of Organic Chemistry, 2000, #9, p.1793-1797；[393] Journal of Organometallic Chemistry, 1982, vol.232, #2, p.C29-C32；[394] Journal of the American Chemical Society, 1987, vol.109, #3, p.908-910；[395] Chemische Berichte, 1912, vol.45, p.3593；[396] Tetrahedron Letters, 2002, vol.43, #21, p.3943-3945；[397] Journal of Organic Chemistry, 1996, vol.61, #3, p.826-830；[398] Journal of Organic Chemistry, 1997, vol.62, #9, p.3019-3020；[399] Tetrahedron, 1995, vol.51, #43, p.11751-11764；[400] Liebigs Annalen, 1995, #4, p.677-684；[401] Tetrahedron Letters, 1986, vol.27, #45, p.5487-5490；[402] Synthetic Communications, 1988, vol.18, #1, p.89-96；[403] European Journal of Inorganic Chemistry, 2012, #21, p.3435-3440；[404] Chemistry - A European Journal, 2015, vol.21, #48, p.17495-17502；[405] Journal of Organometallic Chemistry, 1980, vol.195, #1, p.1-12；[406] RSC Advances, 2016, vol.6, #101, p.99444-99454；[407] Tetrahedron Letters, 2006, vol.47, #1, p.9-12；[408] European Journal of Organic Chemistry, 2000, #9, p.1793-1797；[409] Journal of Organometallic Chemistry, 1982, vol.232, #2, p.C29-C32；[410] Journal of the American Chemical Society, 1987, vol.109, #3, p.908-910；[411] Chemische Berichte, 1912, vol.45, p.3593；[412] Tetrahedron Letters, 2002, vol.43, #21, p.3943-3945；[413] Journal of Organic Chemistry, 1996, vol.61, #3, p.826-830；[414] Journal of Organic Chemistry, 1997, vol.62, #9, p.3019-3020；[415] Tetrahedron, 1995, vol.51, #43, p.11751-11764；[416] Liebigs Annalen, 1995, #4, p.677-684；[417] Tetrahedron Letters, 1986, vol.27, #45, p.5487-5490；[418] Synthetic Communications, 1988, vol.18, #1, p.89-96；[419] European Journal of Inorganic Chemistry, 2012, #21, p.3435-3440；[420] Chemistry - A European Journal, 2015, vol.21, #48, p.17495-17502；[421] Journal of Organometallic Chemistry, 1980, vol.195, #1, p.1-12；[422] RSC Advances, 2016, vol.6, #101, p.99444-99454；[423] Tetrahedron Letters, 2006, vol.47, #1, p.9-12；[424] European Journal of Organic Chemistry, 2000, #9, p.1793-1797；[425] Journal of Organometallic Chemistry, 1982, vol.232, #2, p.C29-C32；[426] Journal of the American Chemical Society, 1987, vol.109, #3, p.908-910；[427] Chemische Berichte, 1912, vol.45, p.3593；[428] Tetrahedron Letters, 2002, vol.43, #21, p.3943-3945；[429] Journal of Organic Chemistry, 1996, vol.61, #3, p.826-830；[430] Journal of Organic Chemistry, 1997, vol.62, #9, p.3019-3020；[431] Tetrahedron, 1995, vol.51, #43, p.11751-11764；[432] Liebigs Annalen, 1995, #4, p.677-684；[433] Tetrahedron Letters, 1986, vol.27, #45, p.5487-5490；[434] Synthetic Communications, 1988, vol.18, #1, p.89-96；[435] European Journal of Inorganic Chemistry, 2012, #21, p.3435-3440；[436] Chemistry - A European Journal, 2015, vol.21, #48, p.17495-17502；[437] Journal of Organometallic Chemistry, 1980, vol.195, #1, p.1-12；[438] RSC Advances, 2016, vol.6, #101, p.99444-99454；[439] Tetrahedron Letters, 2006, vol.47, #1, p.9-12；[440] European Journal of Organic Chemistry, 2000, #9, p.1793-1797；[441] Journal of Organometallic Chemistry, 1982, vol.232, #2, p.C29-C32；[442] Journal of the American Chemical Society, 1987, vol.109, #3, p.908-910；[443] Chemische Berichte, 1912, vol.45, p.3593；[444] Tetrahedron Letters, 2002, vol.43, #21, p.3943-3945；[445] Journal of Organic Chemistry, 1996, vol.61, #3, p.826-830；[446] Journal of Organic Chemistry, 1997, vol.62, #9, p.3019-3020；[447] Tetrahedron, 1995, vol.51, #43, p.11751-11764；[448] Liebigs Annalen, 1995, #4, p.677-684；[449] Tetrahedron Letters, 1986, vol.27, #45, p.5487-5490；[450] Synthetic Communications, 1988, vol.18, #1, p.89-96；[451] European Journal of Inorganic Chemistry, 2012, #21, p.3435-3440；[452] Chemistry - A European Journal, 2015, vol.21, #48, p.17495-17502；[453] Journal of Organometallic Chemistry, 1980, vol.195, #1, p.1-12；[454] RSC Advances, 2016, vol.6, #101, p.99444-99454；[455] Tetrahedron Letters, 2006, vol.47, #1, p.9-12；[456] European Journal of Organic Chemistry, 2000, #9, p.1793-1797；[457] Journal of Organometallic Chemistry, 1982, vol.232, #2, p.C29-C32；[458] Journal of the American Chemical Society, 1987, vol.109, #3, p.908-910；[459] Chemische Berichte, 1912, vol.45, p.3593；[460] Tetrahedron Letters, 2002, vol.43, #21, p.3943-3945；[461] Journal of Organic Chemistry, 1996, vol.61, #3, p.826-830；[462] Journal of Organic Chemistry, 1997, vol.62, #9, p.3019-3020；[463] Tetrahedron, 1995, vol.51, #43, p.11751-11764；[464] Liebigs Annalen, 1995, #4, p.677-684；[465] Tetrahedron Letters, 1986, vol.27, #45, p.5487-5490；[466] Synthetic